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chloroalkali

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Comments

Anonymous

Well done Cody!

Anonymous

Very cool to watch Cody. Thank you for sharing with us.

Jeff Evarts

I confess I'm curious about why you used an MHD pump. Because the electricity was sort "already there and in play"? Regardless, it's very interesting work!

CodysLab

I tried a centerfugal pump but the smallest one I could get just moved way too much mercury.

Anonymous

Neat little design. You probably could improve chlorine yield by reducing the resistance (roughing up the surface of the strip; bringing it closer to the surface of the mercury) and/or lowering the voltage, judging from the color of the gases you're getting a lot of oxygen formation.

Anonymous

When I was designing a prototype once to pump liquid I used a Peristaltic Pump. It was a roller and a silicone tube that pumped liquid. It was really useful as I was using it for food grade and didn't want any moving parts touching the liquid. I don't know if it would pump mercury though.

Jasper

Keeping down that cup of HCl with that thing.. Seems like maybe better have a holder for tubes or clamp for tubes? .. i'm not a chemist, though..

Alexander Thomas

Nice! Maybe you can figure out some way to vent the connecting tubes, in case you cannot avoid the gas building up in them.

Silviu T

A couple of thoughts on your setup: 1. you may want to increase the contact surface especially in the second flask (where NaOH gets generated) by using a larger container; 2. you may want to decrease the total amount of mercury in the system; 3. increase the flow rate of the mercury; the MHD pump is cool and I may steal your concept in a future project, yet I think you would benefit from an increased rate of elimination of sodium amalgam from the first flask by using e.g. a peristaltic pump; that would also allow you to reduce the length of the mercury return path. Also I'm not familiar with gallium-sodium alloy properties, would this work with gallium if it were kept at an appropriate temperature?

Silviu T

I'm sure it would if properly designed and dimensioned for the fluid you're moving. Especially since you're not pumping against a height gradient.

CodysLab

I agree on all your points and I may rebuild it again. The gallium won’t work since it reacts with sodium hydroxide. Though a gallium cell would still make chlorine.

Silviu T

Yeah I forgot that one must think of gallium as "liquid aluminum"

Silviu T

Also as I mentioned in a comment on YT make sure you don't let the chloride concentration in the first flask drop too low or your platinum anode will start dissolving.

Silviu T (edited)

Comment edits

2021-10-11 09:56:20 On an unrelated note, any progress on the thorium project? There have been some recent developments in the thread on scimad, don't know if you read it <a href="http://www.sciencemadness.org/talk/viewthread.php?tid=29927&amp;page=9" rel="nofollow noopener" target="_blank">http://www.sciencemadness.org/talk/viewthread.php?tid=29927&amp;page=9</a>
2018-08-13 10:03:49 On an unrelated note, any progress on the thorium project? There have been some recent developments in the thread on scimad, don't know if you read it <a href="http://www.sciencemadness.org/talk/viewthread.php?tid=29927&page=9" rel="nofollow noopener" target="_blank">http://www.sciencemadness.org/talk/viewthread.php?tid=29927&page=9</a>

On an unrelated note, any progress on the thorium project? There have been some recent developments in the thread on scimad, don't know if you read it <a href="http://www.sciencemadness.org/talk/viewthread.php?tid=29927&page=9" rel="nofollow noopener" target="_blank">http://www.sciencemadness.org/talk/viewthread.php?tid=29927&page=9</a>