Polymers: "Man-Made Miracles" 1954 BF Goodrich; Plastics, Elastomers, Synthetic Rubber... (Patreon)

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Learn about the chemistry in making rubber.

Originally a public domain film, slightly cropped to remove uneven edges, with the aspect ratio corrected, and one-pass brightness-contrast-color correction & mild video noise reduction applied.

The soundtrack was also processed with volume normalization, noise reduction, clipping reduction, and/or equalization (the resulting sound, though not perfect, is far less noisy than the original).

https://en.wikipedia.org/wiki/Synthetic_rubber

Wikipedia license: http://creativecommons.org/licenses/by-sa/3.0/

A synthetic rubber is any artificial elastomer. These are mainly polymers synthesized from petroleum byproducts. About fifteen billion kilograms (thirty-three billion pounds) of rubbers are produced annually, and of that amount two thirds are synthetic. Global revenues generated with synthetic rubbers are likely to rise to approximately US$56 billion in 2020. Synthetic rubber, like natural rubber, has uses in the automotive industry for tires, door and window profiles, hoses, belts, matting, and flooring...

History of synthetic rubber

The expanded use of bicycles, and particularly their pneumatic tires, starting in the 1890s, created increased demand for rubber. In 1909, a team headed by Fritz Hofmann, working at the Bayer laboratory in Elberfeld, Germany, succeeded in polymerizing isoprene, the first synthetic rubber.

The first rubber polymer synthesized from butadiene was created in 1910 by the Russian scientist Sergei Vasiljevich Lebedev. This form of synthetic rubber provided the basis for the first large-scale commercial production by the tsarist empire, which occurred during World War I as a result of shortages of natural rubber. This early form of synthetic rubber was again replaced with natural rubber after the war ended, but investigations of synthetic rubber continued. Russian American Ivan Ostromislensky who moved to New York in 1922 did significant early research on synthetic rubber and a couple of monomers in the early 20th century. Political problems that resulted from great fluctuations in the cost of natural rubber led to the enactment of the Stevenson Act in 1921. This act essentially created a cartel which supported rubber prices by regulating production, but insufficient supply, especially due to wartime shortages, also led to a search for alternative forms of synthetic rubber.

By 1925 the price of natural rubber had increased to the point that many companies were exploring methods of producing synthetic rubber to compete with natural rubber. In the United States, the investigation focused on different materials than in Europe, building on the early laboratory work of Fr Julius Nieuwland, a professor of chemistry at the University of Notre Dame, who developed the synthesis of neoprene.

Studies published in 1930 written independently by Lebedev, the American Wallace Carothers and the German scientist Hermann Staudinger led in 1931 to one of the first successful synthetic rubbers, known as neoprene, which was developed at DuPont under the direction of E. K. Bolton. Neoprene is highly resistant to heat and chemicals such as oil and gasoline, and is used in fuel hoses and as an insulating material in machinery. The company Thiokol applied their name to a competing type of rubber based on ethylene dichloride, which was commercially available in 1930...

In 1935, German chemists synthesized the first of a series of synthetic rubbers known as Buna rubbers. These were copolymers, meaning the polymers were made up from two monomers in alternating sequence. Other brands included Koroseal, which Waldo Semon developed in 1935, and Sovprene, which Russian researchers created in 1940.

B. F. Goodrich Company scientist Waldo Semon developed a new and cheaper version of synthetic rubber known as Ameripol in 1940. Ameripol made synthetic rubber production much more cost effective...

The production of synthetic rubber in the United States expanded greatly during World War II, since the Axis powers controlled nearly all the world's limited supplies of natural rubber by mid-1942. Military trucks needed rubber for tires, and rubber was used in almost every other war machine. The U.S. government launched a major (and largely secret) effort to improve synthetic rubber production. A large team of chemists from many institutions were involved, including Calvin Souther Fuller of Bell Labs. The rubber designated GRS (Government Rubber Styrene), a copolymer of butadiene and styrene, was the basis for U.S. synthetic rubber production during World War II. By 1944, a total of 50 factories were manufacturing it, pouring out a volume of the material twice that of the world's natural rubber production before the beginning of the war. It still represents about half of total world production...